Tetraethoxysilane ( TEOS )

Discussion in 'Alternative Processes' started by Mustafa Umut Sarac, Oct 4, 2013.

  1. Mustafa Umut Sarac

    Mustafa Umut Sarac Member

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    I found this chemical at a recipe of emulsion. Is it toxic, hard to find ?
     
  2. Hexavalent

    Hexavalent Subscriber

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    Not something you want to be playing with!
     
  3. Mustafa Umut Sarac

    Mustafa Umut Sarac Member

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    Ian,

    Why it is used at solgel process at bR emulsion ? Is it possible to replace it ?

    Umut
     
  4. Gerald C Koch

    Gerald C Koch Member

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    TEOS is a volatile liquid and an irritant to mucous membranes and the skin. According to the MSDS it is not particularly toxic.
     
  5. Mustafa Umut Sarac

    Mustafa Umut Sarac Member

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    Why does it necessary to use sol gel step after gelatin step when preparing emulsion ?

    2.2.2. Preparation of sol-gel matrix
    Tetraethoxysilane (TEOS) were used as precursors for the sol-gel glass. TEOS (7 ml), 3.0
    ml of distilled water and 0.1 ml of 0.04 M HC1 were mixed together and sonicated for 20
    min. The resulting product was diluted with an equal volume of distilled water. The resulting
    mixture (0.5 ml) was mixed with 0.25 ml sodium borate buffer solution (pH 9) and (0.1 ml,
    0.2 ml) bR solution to create a film-forming solution. Triethanolamine (TEA) was chosen as
    sensitizing additives. The concentration of chemical additives was in the range of 0.01–0.4
    M. For the preparation of chemically modified films, bR solution was mixed with TEA,
    before mixing with the sol mixture, and afterwards 0.02 ml of the bR-chemical additives
    mixture was added to 0.12 ml of the sol mixture [7,8].
     
  6. Photo Engineer

    Photo Engineer Subscriber

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  7. Mustafa Umut Sarac

    Mustafa Umut Sarac Member

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    PE,

    Do silver gelatin emulsions require such hardeners ? If we pass this step , do protein gelatin emulsion stay soft ?

    Thank you,

    Umut
     
  8. Photo Engineer

    Photo Engineer Subscriber

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    Umut;

    All Silver halide based photographic systems that are intended for wet processing use a hardener. The type of hardener varies from company to company. All emulsions are hard, but they swell giving the effect of a degree of softness.

    PE