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Old 07-15-2008, 02:15 PM   #8 (permalink)
Tom Hoskinson
 
Join Date: Mar 2004
Location: Southern California
Posts: 3,879
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Quote:
Originally Posted by schwefel View Post
I did some searching, on here and am not finding much.

I am looking for the formula for determining the temperature compensation for developers. Based on what I remember from chemistry class, I came up with the following formula:

(10th root of 2)^ΔT for Celcius.

[10th root of 2 raised to the differece in temperature]

When looking at some of the charts I found online, it does not match up.

Anyone out here know the formula?

Thanks,

Jason

Jason
Yes, Jason: The Arrhenius Rate Law is applicable
Rate = A exp(-B/T)

The constants A and B in the Arrhenius rate law are empirical and differ from one reaction to another. However, the empirical values of B are found to be similar for many chemical reactions. One result of this similarity is the useful generalization that for many reactions which occur near room temperature, a temperature increase of 10oC approximately doubles the rate of the reaction.

Reference: http://www.ualberta.ca/~jplambec/che/p102/p02151.htm

I use algebra to obtain the necessary constants from the published Kodak, Ilford, etc time and temperature development data for specific films and developers.
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