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Old 04-02-2007, 08:04 AM   #1 (permalink)
 
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Default Process ECN-2 for Pictorial Use

Title: Process ECN-2 for Pictorial Use

Purpose:

To demonstrate that color motion picture film can be used for pictorial use.

To present a variation of process ECN-2 for the creation of still negatives.

Procedure:

ECN-2 negative film can be gotten for very reasonable prices as short ends but there doesn't seem to be any information about using it for pictorial use, except that it probably a bad idea. Further the ones that want to do it seem intent on using C-41 chemicals instead of the ECN-2 chemicals. Thus producing negatives of less than archival quality even though the formulas for process ECN-2 are published.

The color developer was adapted from its original published form to reflect what I had available and what I could get a hold of for instance Kodak Anti-calcium was removed from the formula and antifoggant AF2000 was also removed as I couldn't source these two chemicals. This necessitated the use of distilled water. Also potassium bromide was substituted for sodium bromide as it was easier to obtain and is less expensive. The stop bath made use of acetic acid instead of sulfuric acid, the fixer was Arista Arifix. It also appears that Kodak has removed formaldehyde from all photographic processes including process ECN-2. After careful reading of the MSDS it was concluded that the chemicals in Final Rinse was the same as what was being offered for process ECN-2.

After warming the water to appropriate temperatures the chemicals were mixed as specified in the formulas section.

Temperature control was achieved by the drift by method were the temperature drop during the color developer step was determined then the change in temperature was divided in half and added to the recommended start temperature. In my case I experienced a drop of 7°F so 7°F/2=3.5. Starting temperature is 103.5°F. Developing time was standard C-41 time of 3.5 minuets. Similar C-41 times was used for the stop, bleach, fix and finial rinse with appropriate rinses between stop and bleach, fix and final rinse.

The rem-jet antihaliation backing was not removed until after the end of the process. After the final rinse step a cotton pad like those for the removal of makeup was used to remove the backing quite easily.

Formulas:

COLOR DEVELOPER
Distilled Water 21 to 38°C (70 to 100°F)
850mL
Sodium Sulfite (Anhydrous)
2.0g
Potassium Bromide (Anhydrous)
1.4g
Sodium Carbonate (Anhydrous)
25.6g
Sodium Bicarbonate
2.7g
CD-3
4.0g
Distilled Water to make
1L

STOP
Water
964mL
Acetic Acid 28%
36mL

BLEACH
Distilled Water 32 to 43°C (90 to 110°F)
900mL
Potassium Ferricyanide (Anhydrous)
40.0g
Potassium Bromide (Anhydrous)
29.0g
Distilled Water to make
1L

Results:

The motion picture film used was Kodak 5205 a Vision-2 250 daylight balanced film shot at an EI of 225. The still film used was Fujifilm Super HQ 200. A amature film was used since the film being compared against is being used outside its intended use. The C-41 negatives were developed and printed on a Fuji Frontier at a local Wal-Mart on Crystal Archive paper the ECN-2 Negatives were developed myself and then printed at the local Wal-Mart using the same machine and paper.

These photographs were taken during overcast weather. The Fuji negatives appear to have been exposed on a bright sunny day with the over saturation and blown highlights associated with this film/paper combination. I shudder to think what this would look like on a bright sunny day. The prints from the ECN-2 negatives have less saturation than the Fuji negatives, but that is another way of saying that the ECN-2 negatives have a more accurate color reproduction compared to the Fuji negatives. Also highlights aren't blown as they are in the Fuji negatives.

Conclusion:

ECN-2 films can be used for pictorial purposes and that the ECN-2 process can be adapted for normal darkroom use.
Attached Images
File Type: jpg C41_1.jpg (102.6 KB, 146 views)
File Type: jpg C41_2.jpg (186.8 KB, 127 views)
File Type: jpg ECN-2_1.jpg (113.8 KB, 110 views)
File Type: jpg ECN-2_2.jpg (112.8 KB, 136 views)
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Old 04-02-2007, 01:15 PM   #2 (permalink)
 
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Guiver, that's a very interesting demonstration. If I am right, the first two photos are on Fuji film and the last two on Kodak Vision?
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Old 04-02-2007, 01:49 PM   #3 (permalink)
 
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Are you sure that the ECN-2 process uses CD-3? At one time it used CD-2.

Also, regarding ECN films, they are built to a contrast value of 0.5 as opposed to professional and consumer negative films with a gamma of 0.6 - 0.65. Therefore, the print material for ECN films has a higher gamma to yield an equivalent positive image.

The normal printing process on Endura or CA paper would yield a print with low contrast and low color saturation and is inappropriate for the ECN family of films.

Use of the wrong developing agent would further reduce contrast and color saturation so please check on that. I have not looked up the ECN formulas in years, so I may be wrong OTOMH like this.

PE
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Old 04-02-2007, 02:41 PM   #4 (permalink)
 
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If you're using home made bleach etc then how do you avoid the formalhyde?
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Old 04-02-2007, 05:50 PM   #5 (permalink)
 
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PE,

I'm pretty sure that it's CD-3 since the formula that I adapted came from "Processing KODAK Motion picture Films Module 7 Process ECN-2 Specifications" document h2407. It can be looked up on the Kodak website.

Nick,
The material used in the final rinse is what matters for image dye stability. Also the bleach was one of many alternatives specified by Kodak. This was only the simplest and cheapest. I'm using Kodak's final rinse which is now formaldehyde free. I checked Kodak's MSDS for there motion picture final rinse. Same chemical.

Mhv,

Correct. The first two are Fuji the second two are Kodak Vision 2.
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Old 04-02-2007, 06:57 PM   #6 (permalink)
 
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I accept that it uses CD3 as I have not looked at an ECN process for a few years, but the contrast is still an issue regarding the quality of the final print.

You just cannot make good prints on current color papers with motion picture negative films even though the overall image quality for the intended purpose may be outstanding.

PE
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Old 04-03-2007, 11:25 AM   #7 (permalink)
 
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PE,

I don't disagree that this isn't an abuse of this material. While it may be difficult to make a good print from this material I don't think that it is impossible. Some subjects may even benefit from the lower contrast. I was actually surprised at how well these prints came out considering that this was done without prior preparation to the machine making the prints (not that I think that they would have made adjustments even if I asked).

I obviously need to experiment with this material to see what it can do. Results to be posted in the forum.
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Old 04-06-2007, 12:13 PM   #8 (permalink)
 
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There was a very similar set of formulae published in Darkroom Techniques a few years ago. The main difference was that the developer was split up into two concentrates so that the mixed developer could be brought to temperature with hot water.

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Old 04-06-2007, 01:56 PM   #9 (permalink)
 
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Has anyone tried the original chemicals for this process in the darkroom, e.g. with a Jobo?
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Old 05-28-2007, 09:35 PM   #10 (permalink)
 
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I'm curious to know how well ECN-2 films do in C-41 chemistry. The remjet backing shouldn't be too hard to deal with, and I'm pretty comfortable with the C-41 process in a home darkroom.
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