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E100VS is a lot easier to work with than Velvia. It scans a lot easier and the colors are a lot more balanced and natural, but very saturated and punchy. It's a great film if that's what you're looking for.
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I have not tried e100vs, but I do like Velvia 50 over Velvia 100F. I also shoot the new Portra 160 and 400 which you can get in 35mm, 120 and 220. I do enjoy the off colors had by expired files at time, so I keep some fairly abused chrome in the fridge. But when I want excellent colors, it's the new Portra for negatives and Velvia 50 for slides.
Fuji 160s is also nice, not as good as the new Portra, but a good all around shooting film.
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