As someone who was in a similar position not so long ago, I cannot recommend these two books highly enough for a person just starting out in film photography. I went through a lot of stuff, both written and off the web but heartily plum for these.
1. Black and white photography: a basic manual (Henry Horenstein) third edition, revised. (Little, Brown - publishers). Available on www.amazon.com
[Basic Photography (Michael Langford). Seventh edition ( Focal Press) is also excellent but Horenstein is less dense and easier to read. www.amazon.co.uk]
2. Composition in Art ( Henry Rankin Moore) (Dover Publications). An invaluable guide to composing a photograph. I believe it is out of print. I bought mine off ebay. A terrific and concise book. Not a word wasted.
Both are applicable to digital. good luck M.