What you plan to do is not recommended for the following reasons--unless you plan to overmat the print right to the edge of the print. But I assume you do not plan to do that. The large white borders of glossy paper will be the brightest thing the eye sees when looking at your print. It will be distracting from the tones of the print itself.
Michael A. Smith
Michael, most art prints have a white border around them. And a matted print has a white border too.